1998 Compilation values for major, minor and trace elements in five
GSJ reference samples, |
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gInstrumental analysis seriesh (N=Number of compiled data, X=mean or
range, STD=standard deviation, RSD=relative STD; |
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in % from SiO2 to T-Fe2O3 and µg g-1 from Ag to Zr, unless otherwise noted) |
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|
Element |
N |
X |
STD |
RSD% |
Element |
N |
X |
STD |
RSD% |
Element |
N |
X |
STD |
RSD% |
|
JR-3
Rhyolite |
@ |
@ |
@ |
Ta |
10 |
36.8 |
3.68 |
10 |
Pb |
7 |
1.46 |
0.610 |
42 |
|
|
|
|
Tb |
7 |
4.29 |
0.297 |
6.9 |
Pr |
4 |
0.385 |
0.033 |
9 |
|
SiO2 |
15 |
72.76 |
0.43 |
0.6 |
Th |
12 |
112 |
4.80 |
4.3 |
Rb |
12 |
2.85 |
1.06 |
37 |
|
Al2O3 |
16 |
11.90 |
0.12 |
1 |
Tl |
2 |
0.623, 1.244 |
@ |
S |
3 |
400-707 |
|
|
Fe2O3 |
5 |
2.61 |
0.066 |
2.5 |
Tm |
3 |
0.79-10 |
|
@ |
Sb |
3 |
0.11-0.13 |
|
|
FeO |
6 |
1.86 |
0.098 |
5.3 |
U |
13 |
21.1 |
3.20 |
15 |
Sc |
13 |
24.7 |
2.06 |
8.3 |
|
MnO |
19 |
0.083 |
0.0043 |
5.2 |
V |
10 |
4.17 |
2.12 |
51 |
Se |
1 |
2 |
|
|
MgO |
16 |
0.050 |
0.013 |
26 |
W |
3 |
4.37-14 |
|
@ |
Sm |
6 |
0.506 |
0.050 |
10 |
|
CaO |
19 |
0.093 |
0.016 |
17 |
Y |
11 |
166 |
4.59 |
2.8 |
Sn |
3 |
0.31-0.8 |
|
|
Na2O |
18 |
4.694 |
0.081 |
1.7 |
Yb |
7 |
20.3 |
1.38 |
7 |
Sr |
14 |
438 |
12.3 |
2.8 |
|
K2O |
21 |
4.294 |
0.141 |
3.3 |
Zn |
14 |
209 |
11.5 |
5.5 |
Ta |
5 |
0.286 |
0.200 |
70 |
|
TiO2 |
21 |
0.213 |
0.013 |
6.1 |
Zr |
15 |
1494 |
115 |
7.7 |
Tb |
6 |
0.152 |
0.070 |
46 |
|
P2O5 |
15 |
0.017 |
0.0070 |
41 |
@ |
|
@ |
Th |
7 |
0.194 |
0.082 |
42 |
|
H2O+ |
3 |
0.55-0.83 |
|
|
JGb-2 Gabbro |
|
@ |
Tl |
1 |
0.03 |
|
|
H2O- |
4 |
0.235 |
0.149 |
63 |
@ |
|
@ |
Tm |
3 |
0.05-0.07 |
|
|
T-Fe2O3 |
21 |
4.724 |
0.087 |
1.8 |
SiO2 |
13 |
46.47 |
0.365 |
0.79 |
U |
3 |
0.03-0.05 |
|
|
L.O.I. |
12 |
0.999 |
0.146 |
15 |
Al2O3 |
15 |
23.48 |
0.272 |
1.16 |
V |
12 |
174 |
5.28 |
3 |
|
Ag |
2 |
0.02, 0.036 |
|
|
Fe2O3 |
5 |
0.616 |
0.149 |
24 |
W |
2 |
1.45, 1.74 |
|
|
As |
4 |
1.08 |
0.636 |
59 |
FeO |
6 |
5.408 |
0.244 |
4.5 |
Y |
10 |
4.53 |
0.899 |
20 |
|
Au (ng g-1) |
1 |
0.3 |
|
|
MnO |
17 |
0.126 |
0.010 |
7.9 |
Yb |
7 |
0.390 |
0.047 |
12 |
|
B |
1 |
11.4 |
|
|
MgO |
16 |
6.183 |
0.119 |
1.9 |
Zn |
13 |
48.5 |
5.47 |
11 |
|
Ba |
12 |
65.8 |
8.05 |
12 |
CaO |
16 |
14.10 |
0.113 |
0.8 |
Zr |
12 |
11.6 |
4.93 |
43 |
|
Be |
6 |
7.58 |
0.831 |
11 |
Na2O |
14 |
0.921 |
0.027 |
2.9 |
@ |
@ |
@ |
@ |
|
Bi |
2 |
0.1, 0.21 |
|
|
K2O |
15 |
0.059 |
0.0073 |
12 |
JH-1 Hornblendite |
|
Br |
1 |
3 |
|
|
TiO2 |
16 |
0.561 |
0.016 |
2.9 |
|
C |
2 |
230, 480 |
|
|
P2O5 |
12 |
0.017 |
0.0080 |
47 |
SiO2 |
10 |
48.18 |
0.695 |
1.4 |
|
Cd |
2 |
0.064, 0.1 |
|
|
H2O+ |
3 |
1.26-1.77 |
|
@ |
Al2O3 |
13 |
5.657 |
0.248 |
4.4 |
|
Ce |
12 |
327 |
22.3 |
6.8 |
H2O- |
5 |
0.142 |
0.028 |
20 |
Fe2O3 |
4 |
1.385 |
0.409 |
30 |
|
Co |
11 |
0.980 |
0.516 |
53 |
T-Fe2O3 |
17 |
6.691 |
0.137 |
2 |
FeO |
4 |
8.085 |
0.262 |
3.2 |
|
Cr |
11 |
3.49 |
1.55 |
44 |
L.O.I. |
10 |
1.357 |
0.154 |
11 |
MnO |
11 |
0.190 |
0.0084 |
4.4 |
|
Cs |
11 |
1.02 |
0.129 |
13 |
As |
2 |
0.86, 1.06 |
|
@ |
MgO |
13 |
16.73 |
0.593 |
3.5 |
|
Cu |
10 |
2.87 |
1.17 |
41 |
Au (ng g-1) |
1 |
0.7 |
|
@ |
CaO |
13 |
15.02 |
0.200 |
1.3 |
|
Dy |
4 |
21.5 |
8.53 |
40 |
B |
1 |
4.9 |
|
@ |
Na2O |
13 |
0.707 |
0.027 |
3.8 |
|
Er |
3 |
4.29-18.8 |
|
|
Ba |
11 |
36.5 |
7.75 |
21 |
K2O |
14 |
0.526 |
0.021 |
4 |
|
Eu |
9 |
0.527 |
0.106 |
20 |
Be |
1 |
0.2 |
|
@ |
TiO2 |
11 |
0.665 |
0.017 |
2.6 |
|
F |
2 |
320, 1800 |
|
|
Bi |
1 |
0.022 |
|
@ |
P2O5 |
11 |
0.0991 |
0.0102 |
10 |
|
Ga |
7 |
36.6 |
1.57 |
4.3 |
C |
2 |
710, 1050 |
|
@ |
H2O+ |
1 |
1.82 |
|
|
Gd |
4 |
19.7 |
3.75 |
19 |
Cd |
1 |
0.07 |
|
@ |
H2O- |
2 |
0.13, 0.23 |
|
|
Hf |
7 |
40.3 |
1.56 |
3.9 |
Ce |
8 |
2.98 |
0.378 |
13 |
T-Fe2O3 |
13 |
10.27 |
0.164 |
1.6 |
|
Hg (ng g-1) |
2 |
1.15, 3.4 |
|
|
Co |
17 |
25.8 |
1.60 |
6.2 |
L.O.I. |
8 |
1.780 |
0.324 |
18 |
|
Ho |
4 |
4.66 |
2.51 |
54 |
Cr |
15 |
125 |
4.91 |
3.93 |
Ag |
1 |
0.02 |
|
La |
14 |
179 |
12.5 |
7 |
Cs |
7 |
0.510 |
0.091 |
18 |
As |
2 |
0.8, 1.12 |
|
|
Li |
3 |
118-123.669 |
|
|
Cu |
12 |
11.4 |
1.79 |
16 |
B |
1 |
10.8 |
|
|
Lu |
7 |
2.75 |
0.375 |
14 |
Dy |
4 |
0.598 |
0.067 |
11 |
Ba |
12 |
106 |
14.2 |
13 |
|
Mo |
5 |
0.491 |
0.157 |
32 |
Er |
4 |
0.362 |
0.055 |
15 |
Be |
2 |
0.4, 0.45 |
|
|
Nb |
13 |
510 |
30.4 |
6 |
Eu |
8 |
0.585 |
0.079 |
14 |
Bi |
2 |
0.067, 0.2 |
|
|
Nd |
10 |
107 |
7.83 |
7.3 |
F |
1 |
70 |
|
@ |
Br |
1 |
2.20 |
|
Ni |
3 |
1.1-1.929 |
|
|
Ga |
8 |
15.9 |
1.35 |
8.5 |
C |
1 |
1630 |
|
|
Pb |
13 |
32.8 |
6.24 |
19 |
Gd |
3 |
0.39-0.554 |
|
@ |
Cd |
1 |
0.1 |
2.51 |
|
Pr |
6 |
33.1 |
3.85 |
12 |
Hf |
6 |
0.252 |
0.068 |
27 |
Ce |
9 |
17.6 |
2.38 |
14 |
|
Rb |
17 |
453 |
12.2 |
2.7 |
Hg (ng g-1) |
2 |
1.77, 2.0 |
|
@ |
Co |
15 |
51.5 |
3.76 |
7 |
|
S |
2 |
39, 152 |
|
|
Ho |
4 |
0.145 |
0.013 |
9 |
Cr |
14 |
616 |
54.4 |
9 |
|
Sb |
4 |
0.166 |
0.040 |
24 |
La |
9 |
1.45 |
0.303 |
21 |
Cs |
7 |
0.866 |
0.218 |
25 |
|
Sc |
7 |
0.499 |
0.060 |
12 |
Li |
3 |
15.2-16 |
|
@ |
Cu |
9 |
8.61 |
1.33 |
15 |
|
Se |
2 |
3, <0.2 |
|
|
Lu |
6 |
0.062 |
0.014 |
23 |
Dy |
5 |
2.51 |
0.362 |
14 |
|
Sm |
10 |
21.3 |
1.12 |
5.3 |
Mo |
5 |
0.424 |
0.228 |
54 |
Er |
5 |
1.24 |
0.159 |
13 |
|
Sn |
5 |
17.4 |
2.25 |
13 |
Nb |
8 |
1.91 |
0.666 |
35 |
Eu |
7 |
0.859 |
0.056 |
7 |
|
Sr |
16 |
10.4 |
1.66 |
16 |
Nd |
6 |
1.84 |
0.231 |
13 |
F |
1 |
240 |
|
|
|
|
|
Ni |
11 |
13.6 |
1.90 |
14 |
Ga |
7 |
7.90 |
1.17 |
15 |
|
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|
Element |
N |
X |
STD |
RSD% |
Element |
N |
X |
STD |
RSD% |
Element |
N |
X |
STD |
RSD% |
|
|
|
|
|
Gd |
4 |
2.67 |
0.251 |
9 |
Cs |
7 |
0.687 |
0.124 |
18 |
L.O.I. |
2 |
16.05, 16.05 |
|
|
|
|
|
Hf |
7 |
1.35 |
0.156 |
12 |
Cu |
5 |
1.25 |
0.398 |
32 |
As |
5 |
75.4 |
3.54 |
4.7 |
|
|
|
|
|
Hg (ng g-1) |
1 |
1.9 |
|
|
Dy |
5 |
0.374 |
0.050 |
13 |
Au (ng g-1) |
2 |
0.8,
1.1 |
|
|
|
|
|
|
Ho |
5 |
0.532 |
0.081 |
15 |
Er |
5 |
0.295 |
0.046 |
16 |
B |
1 |
138 |
|
|
|
|
|
|
La |
9 |
7.92 |
1.02 |
13 |
Eu |
6 |
0.155 |
0.014 |
9 |
Ba |
7 |
1714 |
74.0 |
4.3 |
|
|
|
|
|
Li |
3 |
12-12.18 |
|
|
Ga |
6 |
23.5 |
1.37 |
5.8 |
Be |
1 |
7.8 |
|
|
Lu |
7 |
0.165 |
0.031 |
19 |
Gd |
5 |
0.267 |
0.027 |
10.1 |
Bi |
3 |
4.2-4.48 |
|
|
Mo |
5 |
0.770 |
0.167 |
22 |
Ge |
1 |
0.67 |
|
@ |
Br |
1 |
34.00 |
|
Nb |
11 |
4.19 |
1.14 |
27 |
Hf |
5 |
1.15 |
0.121 |
11 |
C |
1 |
905 |
|
|
Nd |
8 |
11.6 |
1.10 |
9 |
Hg (ng g-1) |
1 |
0.5 |
|
@ |
Cd |
3 |
13.47-20 |
|
|
Ni |
9 |
58.2 |
8.19 |
14 |
Ho |
6 |
0.094 |
0.015 |
16 |
Ce |
6 |
277 |
12.4 |
4.5 |
|
Pb |
7 |
2.55 |
0.993 |
39 |
Ir |
1 |
0.016 |
|
@ |
Co |
8 |
1732 |
68.7 |
4 |
|
Pr |
4 |
2.31 |
0.176 |
8 |
La |
7 |
1.21 |
0.201 |
17 |
Cr |
8 |
26.6 |
4.97 |
19 |
|
Rb |
14 |
14.4 |
1.37 |
10 |
Li |
4 |
15.3 |
1.50 |
9.8 |
Cs |
5 |
0.604 |
0.333 |
55 |
|
S |
2 |
400, 650 |
|
|
Lu |
6 |
0.076 |
0.011 |
14 |
Cu |
7 |
11132 |
993 |
8.9 |
|
Sb |
2 |
0.063, 0.07 |
|
|
Mo |
3 |
0.04-0.06 |
|
@ |
Dy |
4 |
28.3 |
1.89 |
6.7 |
|
Sc |
10 |
77.6 |
3.79 |
4.9 |
Nb |
5 |
0.514 |
0.594 |
116 |
Er |
5 |
14.6 |
1.85 |
13 |
|
Sm |
7 |
3.05 |
0.186 |
6.1 |
Nd |
6 |
1.22 |
0.117 |
9.6 |
Eu |
6 |
7.58 |
0.320 |
4.2 |
|
Sn |
3 |
0.80-1 |
|
|
Ni |
5 |
1.11 |
0.874 |
79 |
F |
1 |
7430 |
|
|
Sr |
14 |
153 |
5.48 |
3.6 |
Os (ng g-1) |
1 |
0.019 |
|
@ |
Ga |
2 |
32.51, 41.7 |
|
|
Ta |
5 |
0.226 |
0.022 |
9.7 |
Pb |
7 |
4.89 |
0.405 |
8 |
Gd |
4 |
29.8 |
2.51 |
8.4 |
|
Tb |
7 |
0.517 |
0.081 |
16 |
Pd (ng g-1) |
1 |
0.13 |
|
@ |
Ge |
1 |
1.51 |
|
|
Th |
9 |
1.44 |
0.255 |
18 |
Pr |
5 |
0.318 |
0.036 |
11.3 |
Hf |
4 |
6.23 |
0.236 |
3.8 |
|
Tl |
1 |
0.095 |
|
|
Pt (ng g-1) |
1 |
0.089 |
|
@ |
Ho |
5 |
5.76 |
0.482 |
8.4 |
|
Tm |
4 |
0.194 |
0.013 |
7 |
Rb |
11 |
66.3 |
2.70 |
4.1 |
In |
1 |
0.25 |
|
|
U |
6 |
0.583 |
0.364 |
62 |
Rh |
1 |
0.010 |
|
@ |
Ir |
1 |
0.58 |
|
|
V |
11 |
228 |
7.86 |
3.4 |
Ru (ng g-1) |
1 |
0.030 |
|
@ |
La |
6 |
122 |
2.72 |
2.2 |
|
W |
1 |
1.19 |
|
|
S |
1 |
13 |
|
@ |
Li |
3 |
69-74 |
|
|
Y |
12 |
13.7 |
1.12 |
8.2 |
Sb |
7 |
0.148 |
0.032 |
22 |
Lu |
7 |
2.07 |
0.248 |
12 |
|
Yb |
8 |
1.16 |
0.134 |
12 |
Sc |
2 |
0.01, 3.0 |
|
@ |
Mo |
6 |
318 |
21.3 |
6.7 |
|
Zn |
10 |
61.8 |
6.00 |
9.7 |
Sm |
6 |
0.274 |
0.037 |
14 |
Nb |
3 |
22.3-33 |
|
|
Zr |
11 |
48.3 |
5.30 |
11 |
Sn |
6 |
0.169 |
0.058 |
34 |
Nd |
6 |
137 |
8.31 |
6.1 |
|
@ |
@ |
@ |
@ |
|
Sr |
11 |
19.3 |
3.09 |
16 |
Ni |
11 |
12632 |
828 |
6.6 |
|
JSy-1
Syenite |
|
|
Ta |
3 |
0.008-0.02 |
|
@ |
Os (ng g-1) |
1 |
0.037 |
|
|
|
|
|
Tb |
4 |
0.057 |
0.021 |
37 |
Pb |
9 |
430 |
24.7 |
5.7 |
|
SiO2 |
7 |
60.02 |
0.548 |
0.9 |
Th |
6 |
0.232 |
0.067 |
29 |
Pd (ng g-1) |
1 |
1.6 |
|
|
Al2O3 |
9 |
23.17 |
0.329 |
1.4 |
Tl |
3 |
0.61-1.515 |
|
@ |
Pr |
4 |
31.4 |
1.38 |
4.4 |
|
MnO |
5 |
0.0024 |
0.00083 |
35 |
Tm |
5 |
0.053 |
0.0079 |
15 |
Pt (ng g-1) |
2 |
41, 110 |
|
|
MgO |
6 |
0.016 |
0.0046 |
29 |
U |
5 |
0.197 |
0.119 |
60 |
Rb |
7 |
10.9 |
1.49 |
14 |
|
CaO |
8 |
0.251 |
0.023 |
9.2 |
V |
7 |
2.06 |
1.17 |
57 |
Rh |
1 |
1.9 |
|
|
Na2O |
10 |
10.74 |
0.248 |
2.3 |
W |
2 |
0.050, 0.07 |
|
@ |
Ru (ng g-1) |
1 |
5 |
|
|
K2O |
11 |
4.816 |
0.145 |
3 |
Y |
7 |
2.62 |
0.340 |
13 |
S |
2 |
800, 1080 |
|
|
TiO2 |
2 |
0.001, 0.002 |
|
|
Yb |
6 |
0.405 |
0.032 |
7.9 |
Sb |
7 |
37.5 |
1.50 |
4 |
|
P2O5 |
4 |
0.0135 |
0.0076 |
56 |
Zn |
8 |
3.18 |
0.829 |
26 |
Sc |
4 |
13.0 |
0.54 |
4.2 |
|
H2O+ |
1 |
0.27 |
|
|
Zr |
8 |
70.2 |
2.66 |
3.8 |
Sm |
6 |
30.2 |
1.14 |
3.8 |
|
H2O- |
1 |
0.11 |
|
|
@ |
@ |
@ |
@ |
@ |
Sn |
4 |
4.37 |
2.34 |
54 |
|
T-Fe2O3 |
9 |
0.0837 |
0.0095 |
11 |
JMn-1 Manganese Nodule |
|
@ |
Sr |
9 |
792 |
57.0 |
7.2 |
|
L.O.I. |
6 |
0.540 |
0.161 |
30 |
@ |
|
@ |
Ta |
4 |
0.635 |
0.057 |
9 |
|
As |
3 |
0.83-0.94 |
|
|
SiO2 |
5 |
14.11 |
0.126 |
0.9 |
Tb |
7 |
4.81 |
0.443 |
9.2 |
|
Au (ng g-1) |
1 |
0.094 |
|
|
Al2O3 |
8 |
4.297 |
0.145 |
3.4 |
Th |
6 |
11.7 |
0.737 |
6 |
|
B |
1 |
14.5 |
|
|
MnO |
7 |
33.09 |
0.561 |
1.7 |
Tl |
2 |
76.44, 211 |
|
|
Ba |
8 |
15.7 |
4.84 |
31 |
MgO |
8 |
3.115 |
0.182 |
5.8 |
Tm |
5 |
2.14 |
0.216 |
10 |
|
Be |
4 |
0.795 |
0.212 |
27 |
CaO |
8 |
2.909 |
0.103 |
3.5 |
U |
5 |
5.01 |
0.407 |
8.1 |
|
Bi |
2 |
0.006, 0.012 |
|
|
Na2O |
8 |
2.797 |
0.134 |
4.8 |
V |
8 |
424 |
21.3 |
5 |
|
C |
1 |
340 |
|
|
K2O |
9 |
0.944 |
0.065 |
6.9 |
W |
4 |
45.3 |
11.3 |
25 |
|
Cd |
1 |
0.04 |
|
TiO2 |
7 |
1.061 |
0.030 |
2.8 |
Y |
6 |
111 |
9.12 |
8.2 |
|
Ce |
6 |
2.62 |
0.302 |
12 |
P2O5 |
6 |
0.535 |
0.020 |
3.7 |
Yb |
6 |
13.8 |
0.646 |
4.7 |
|
Co |
4 |
0.156 |
0.140 |
90 |
H2O+ |
3 |
7.89-7.93 |
|
@ |
Zn |
9 |
1068 |
109 |
10 |
|
Cr |
7 |
2.00 |
1.15 |
58 |
T-Fe2O3 |
8 |
14.40 |
0.411 |
2.9 |
Zr |
5 |
344 |
22.9 |
6.7 |
|
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